Aluminum sulfide, additionally called dialuminium trisulfide, is one ionic link of aluminum and sulfur stood for by the chemistry formula Al2S3 <1, 2>. It exists in various crystalline forms and also hydrolyzes to aluminum hydroxide/oxide <3, 4>.
Aluminum Sulfide Identification | |
CAS Number | 1302-81-4 <1, 2> |
PubChem CID | 16684788 <6> |
ChemSpider ID | 140154 <1> |
EC Number | 215-109-0 <1, 2> |
InChI Key | ZPXDOGRYMSWBBM-UHFFFAOYSA-N <6> |
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Aluminum Sulfide Formula
How is Aluminum Sulfide Prepared
Its synthetic through direct heating the aluminum and sulfur can be represented by the complying with equation <7>:
2Al + 3S → Al2S3
However, the reaction is extremely exothermic, and it is not desirable to warmth the whole mixture <7>. Also, sulfur is a volatile reactant the melts away prior to the reaction takes ar <7>. Therefore, lead sulfide is frequently used because that the preparation of Al2S3 <7>:
2Al + 3PbS → Al2S3 + 3Pb

Aluminum Sulfide
Reactions with various other Compounds
Aluminum Sulfide and Water
When aluminum sulfide is exposed to moisture in the atmosphere, it undergoes hydrolysis reaction to form aluminum hydroxide and hydrogen sulfide <5>.
Al2S3 + 6H2O → 2Al(OH)3 + 3H2S
Aluminum Sulfide and Hydrochloric Acid
Aluminum sulfide top top reacting through hydrochloric acid develops hydrogen sulfide and aluminum chloride, together shown listed below <8>:
Al2S3 + 6HCl → 2AlCl3 + 3H2S

Aluminum Sulfide Lewis Structure
Properties and also Characteristics that Aluminum Sulfide
General Properties | |
Molar Mass/Molecular Weight | 150.158 g/mol <1> |
Physical Properties | |
Color and also Appearance | Gray powder or granules <2> |
Melting Point | 1,100 °C, 2,012 °F <2> |
Boiling Point | 1,500 °C, 2,732 °F <2> |
Density | 2.32 g cm-3 <2> |
State of issue at room temperature (solid/liquid/gas) | Solid <2> |
Solubility | Insoluble in (CH3)2CO (acetone) <9> |
Solubility in Water | Reacts and decomposes in H2O <9> |
Heat volume (C) | 105.1 J/mol K |
Standard Molar Enthalpy | -724 kJ/mol <9> |
Standard Molar Entropy | 116.9 J/mol K |
Atomic Properties | |
Crystal Structure | Trigonal, tetragonal, hexagonal <3, 4> |

Aluminum Sulfide crystal Structure
What is It supplied for
Producing necessary compounds prefer ethanethiol and chemicals compelled for tanning and also making file <10>Preparing hydrogen sulfide that has actually several commercial uses <11>Is Aluminum Sulfide Toxic
Exposure to aluminum sulfide can cause skin and severe eye wake up <12>. Inhalation the dust, vapor, or fumes deserve to cause difficulty in breath <12>.
References:
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